Formation of 5-membered metallacycles at iPrPCPIr by C–H, O–H, and C–CO bond cleavage
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چکیده
منابع مشابه
Reactivity of iron complexes containing monodentate aminophosphine ligands – Formation of four-membered carboxamido-phospha-metallacycles
Treatment of [FeCp(CO)2Cl] with 1 equiv of the amidophosphine ligands Li[R2PNR'] (R = Ph, iPr, R' = iPr, tBu, Cy) afforded complexes of the type [FeCp(CO)(κ2(C,P)-(C 000000000000 000000000000 000000000000 111111111111 000000000000 111111111111 000000000000 000000000000 000000000000 O)-NiPr-PPh2)] (1a), [FeCp(CO)(κ2(C,P)-(CO)-NtBu-PPh2)] (1b), and [FeCp(CO)(κ2(C,P)-(CO)-NCy-PiPr2)] (1c) in 40-50...
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ژورنال
عنوان ژورنال: Polyhedron
سال: 2016
ISSN: 0277-5387
DOI: 10.1016/j.poly.2016.03.018